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[1]贾思媛,王伯周,郝成刚,等.二氨基-3-硝基-1,2,4-三唑-的合成及晶体结构[J].火炸药学报,2012,35(3):23-26.
 JIA Si-yuan,WANG Bo-zhou,HAO Cheng-gang,et al.Synthesis and Crystal Structure of 1,5-Diamino-3-nitro-1,2,4-triazole[J].,2012,35(3):23-26.
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二氨基-3-硝基-1,2,4-三唑-的合成及晶体结构()
     
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《火炸药学报》[ISSN:1007-7812/CN:61-1310/TJ]

卷:
35
期数:
2012年第3期
页码:
23-26
栏目:
出版日期:
2012-06-30

文章信息/Info

Title:
Synthesis and Crystal Structure of 1,5-Diamino-3-nitro-1,2,4-triazole
作者:
贾思媛王伯周郝成刚张海昊周群王锡杰
西安近代化学研究所
Author(s):
JIA Si-yuanWANG Bo-zhouHAO Cheng-gangZHANG Hai-haoZHOU QunWANG Xi-jie
Xi懡渀 Modern Chemistry Research Institute
关键词:
有机化学35-二硝基-124-三唑铵盐氨化反应15-二氨基-3-硝基-124-三唑
Keywords:
organic chemistryammonium salt of 35-dinitro-124-triazoleaminate15-diamino-3-nitro-124-triazole
分类号:
-
DOI:
-
文献标志码:
A
摘要:
以3,5-二硝基-1,2,4三唑铵盐为原料,经还原、氨化合成出1,5-二氨基-3-硝基-1,2,4-三唑(BANT),总收率为64%,采用红外光谱、核磁共振光谱、质谱以及元素分析等进行了结构表征。培养了BANT单晶,四圆衍射分析表明,BANT晶体属于单斜晶系,晶体空间群为C2/c,晶包参数为:a=11.672 (4)nm,b=3.7395(13) nm, β= 1.463°,c=13.365(5)nm, V=564.5(3)nm3, Dc=1.696g/cm3
Abstract:
A novel energetic compound 1,5-diamino-3-nitro-1,2,4-triazole (BANT) was synthesized by reduction and amination using ammonium salt of 3,5-dinitro-1,2,4-triazole as starting material with overall yield of 64%.The structure of BANT was characterized by IR,NMR,MS and elemantal analysis.The single crystal of BANT was cultured and its crystal structure was determined by X-ray crystallogaphy.The results show that the crystal is monoclinic,space group C2/c with crystal parameters of:a=11.672(4)nm,b=3.7395(13) nm,β=1.463°,c=13.365(5)nm,V=564.5(3)nm3,Dc=1.696g/cm3.

参考文献/References:

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